L'andata dei playoff che determina l'accesso ai gironi di Champions League ha visto due vittorie in trasferta e tre pareggi. Il Porto si è imposto nel big match contro i francesi del Lilla per 1-0, grazie alla rete di Héctor Herrera al 61' che ha sfruttato il cross di Christian Tello. Bene anche lo Zenit di San Pietroburgo allenato da Villas Boas, che ha superato lo Standard Liegi con il punto decisivo di Oleg Shatov al 16' su passaggio del brasiliano Hulk.
Gli altri incontri Maribor-Celtic (in gol Bohar 6' e McGregor 14'), Aalborg-Apoel Nicosia (Thomsen 16', Vinicius 54') e Slovan Bratislava-Bate Borisov (autorete di Jablonsky al 44', pareggio di Vittek all'80') sono tutti terminati senza vincitori con il punteggio di 1-1. Le gare di ritorno sono in programma tra una settimana (26-27.8).
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